校園頭條

【研究發展處訊】

化學系王志傑特聘教授及何美霖特聘教授發表最新期刊論文

 Synthesis, Structural Characterization and Ligand- Enhanced Photo-Induced Color-Changing Behavior of Two Hydrogen-Bonded Ho(III)-Squarate Supramolecular Compounds

 作者：Chih-Chieh Wang , Szu-Yu Ke, Yun Feng, Mei-Lin Ho, Chung-Kai Chang, Yu-Chun Chuang and Gene-Hsiang Lee

 POLYMERS

卷：11  期：8  文獻號碼：1369

出版日期：2019年8月(SCI)

 摘要：

Two coordination polymers (CPs) with chemical formulas, [Ho₂(C₄O₄)₂(C₂O₄)(H₂O)₈]·4H₂O (1) and [Ho(C₄O₄)_1.5(H₂O)₃] (2), (C₄O₄^2- = dianion of squaric acid, C₂O₄^2- = oxalate), have been synthesized and their structures were determined by single-crystal X-ray diffractometer (XRD). In compound 1, the coordination environment of Ho(III) ion is eight-coordinate bonded to eight oxygen atoms from two squarate, one oxalate ligands and four water molecules. The squarates and oxalates both act as bridging ligands with _1,2-bis-monodentate and bis-chelating coordination modes, respectively, connecting the Ho(III) ions to form a one-dimensional (1D) ladder-like framework. Adjacent ladders are interlinked via O-HO hydrogen bonding interaction to form a hydrogen-bonded two-dimensional (2D) layered framework and then arranged orderly in an AAA manner to construct its three-dimensional (3D) supramolecular architecture. In compound 2, the coordination geometry of Ho(III) is square-antiprismatic eight coordinate bonded to eight oxygen atoms from five squarate ligands and three water molecules. The squarates act as bridging ligands with two coordination modes, _1,2,3-trismonodentate and _1,2-bis-monodentate, connecting the Ho(III) ions to form a 2D bi-layered framework. Adjacent 2D frameworks are then parallel stacked in an AAA manner to construct its 3D supramolecular architecture. Hydrogen bonding interactions between the squarate ligands and coordinated water molecules in 1 and 2 both play important roles on the construction of their 3D supramolecular assembly. Compounds 1 and 2 both show remarkable ligand-enhanced photo-induced color-changing behavior, with their pink crystals immediately turning to yellow crystals under UV light illumination.

Keywords

coordination polymer; metal-organic framework; hydrogen bond; supramolecular architecture; color change

(研究事務組小提醒)教師如有最新發表於AHCI、SSCI、SCI、EI、TSSCI、THCI、「東吳大學外語學門獎勵名單」之期刊論文，歡迎將相關資訊e-mail至rad@scu.edu.tw，研究發展處將會公告於校園頭條，以廣交流。

【文圖/研究事務組郭玟圻專員】