【研究發展處訊】

化學系江建緯副教授發表最新期刊論文

Synergistic Photoredox and Electrochemical Catalysis in Organic Synthesis and Late-Stage Functionalizations

作者：Sun, Ci-Yang (孫啟洋); Lin, Ting-Jun (林亭君); Chen, Yu-Yu (陳宥羽); Li, Hung-Li (李弘曆); Chiang, Chien-Wei (江建緯)

ChemCatChem (SCI)

Early Access：FEB 2024

DOI：10.1002/cctc.202301537

摘要：

This review delves into the innovative field of interfacial photoelectrochemical (iPEC) and photoelectrochemical (PEC) catalysis, the dynamic synthesis methodologies that seamlessly integrates electrochemical and photoredox catalysis for efficient and environmentally friendly reactions. Utilizing minute quantities of photocatalysts, visible light becomes a powerful tool, generating transient excited states to catalyze a spectrum of reactions through single-electron oxidation or reduction events. The review categorizes recent advancements, highlighting applications in organic synthesis, late-stage modifications, and the distinctive features of photoelectrochemical methodology. Despite being in its early stages, this synergistic approach holds great promise for propelling organic synthesis forward, with potential applications in large-scale synthesis and diverse late-stage functionalizations, including asymmetric catalysis and bioconjugation strategies for biomolecule modifications.

本文探討了界面光電化學（iPEC）和光電化學（PEC）催化的創新領域，這是一類通過將電化學和光氧化還原催化相結合的動態合成方法學，可以實現高效和環保的反應。舉例來說，利用微量的光催化劑，可見光成即可促進光催化劑產生短暫的激發態，並通過單電子氧化或還原來催化一系列反應的發生。本文亦將近期相關研究的進展分為不同類別，突出了在有機合成、後期修飾以及光電化學方法的獨特特點中的應用。這種協同作用的方法對推動有機合成有很大的潛力，可能應用於大規模合成和各種後期功能化，包括對生物分子進行不對稱催化和生物共軛策略進行修飾。

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【文圖/研究事務組謝明秀專員】