【研究發展處訊】

化學系王志傑教授及何美霖教授發表最新期刊論文

Four Mixed-Ligand Zn(II) Three-Dimensional Metal-Organic Frameworks: Synthesis, Structural Diversity, and Photoluminescent Property

作者：Chih-Chieh Wang, Szu-Yu Ke, Chia-Wen Cheng, Yu-Wen Wang, Hsiao-Shan Chiu, Yu-Chien Ko, Ning-Kuei Sun, Mei-Lin Ho, Chung-Kai Chang, Yu-Chun Chuang and Gene-Hsiang Lee

POLYMERS

卷：9  期：12  文獻號碼：644

出版日期：2017年12月(SCI)

摘要：

Assemblies of four three-dimensional (3D) mixed-ligand coordination polymers (CPs) having formulas, {[Zn₂(bdc)₂(4-bpdh)]·C₂H₅OH·2H₂O}_n (1), [Zn(bdc)(4-bpdh)]_n (2), {[Zn₂(bdc)₂(4-bpdh)₂]·(4-bpdh)}_n (3), and {[Zn(bdc)(4-bpdh)]·C₂H₅OH}_n (4) (bdc²⁻ = dianion of 1,4-benzenedicarboxylic acid, 4-bpdh = 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene) have been synthesized and structurally characterized by single-crystal X-ray diffraction method. Structural determination reveals that the coordination numbers (geometry) of Zn(II) ions in 1, 2, 3, and 4 are five (distorted square-pyramidal (SP)), six (distorted octahedral (O_h)), five (trigonal-bipyramidal (TBP)), and four (tetrahedral (T_d)), respectively, and are bridged by 4-bpdh with bis-monodentate coordination mode and bdc²⁻ ligands with bis-bidentate in 1, chelating/bidentate in 2, bis-monodentate and bis-bidentate in 3, and bis-monodentate in 4, to generate two-fold interpenetrating 3D cube-like metal-organic framework (MOF) with pcu topology, non-interpenetrating 3D MOF, two-fold interpenetrating 3D rectangular-box-like MOF with pcu topology and five-fold interpenetrating diamondoid-like MOF with dia topology, respectively. These different intriguing architectures indicate that the coordination numbers and geometries of Zn(II) ions, coordination modes of bdc²⁻ ligand, and guest molecules play important roles in the construction of MOFs and the formation of the structural topologies and interpenetrations. Thermal stabilities, and photoluminescence study of 1–4 were also studied in detail. The complexes exhibit ligands based photoluminescence properties at room temperature.

Keywords

coordination polymer; metal-organic framework; structural topology; interpenetration; photoluminescence

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